The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / t-C4H9O2,(CH3)3CO2 / Lightfoot(1992)_298K_210-280nm(rec)

DATAFILE: t-C4H9O2,(CH3)3CO2_Lightfoot(1992)_298K_210-280nm(rec).txt
NAME: 1,1,1-dimethylethylperoxy radical, tert-butylperoxy radical
FORMULA: t-C4H9O2,(CH3)3CO2
AUTHOR(YEAR): Lightfoot(1992)
T: 298K
λ: 210-280nm(rec)
BIBLIOGRAPHY: P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I
COMMENTS: Recommendation based on a smooth fit to the data of

C. Anastasi, I.W.M. Smith, and D.A. Parkes, "Flash photolysis study of the spectra of CH3O2 and C(CH3)3O2 radicals and the kinetics of their mutual reactions and with NO," J. Chem. Soc. Faraday Trans. I 74, 1693-1701 (1978), and

P.D. Lightfoot, P. Roussel, B. Veyret, and R. Lesclaux, "Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals," J. Chem.Soc. Faraday Trans. 86, 2927-2936 (1990)

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